Non-Linear Signal Detection Improvement by Radiation Damping in Single-Pulse NMR Spectra

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Non-Linear Signal Detection Improvement by Radiation Damping in Single-Pulse NMR Spectra

When NMR lines overlap and at least one of them is affected by radiation damping, the resonance line shapes of all lines are no longer Lorentzian. We report the appearance of narrow signal distortions, which resemble hole-burnt spectra. This new experimental phenomenon facilitates the detection of tiny signals hidden below the main resonance. Theoretical analysis based on modified Maxwell-Bloch...

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ژورنال

عنوان ژورنال: ChemPhysChem

سال: 2012

ISSN: 1439-4235

DOI: 10.1002/cphc.201100724